Preheat the oven to 425ºF.
Pat pork chops dry with paper towels and season with salt, pepper and granulated garlic. Combine pan sauce ingredients together in a small bowl and leave to the side.
Slice the red onion thinly and leave to the side. Quarter creamer potatoes (if using another type of potato, cut into ½” dice).
Place potatoes in a microwave safe dish and microwave for 2 minutes. Leave to the side.
Meanwhile, heat oil in the dutch oven over medium-high heat. When the oil is hot and looks shimmery, add the pork. Sear each side for 3 minutes, until golden brown.
Transfer pork chops to a plate and turn the dutch oven heat off. Check the internal temperature of the pork chops; if they are thinner, they may already be close to the 145°F USDA recommended internal temperature. If they are already at temperature, continue with the steps until potatoes are fork tender. If they are not at temperature, continue along all steps.
Turn to low heat and add the thinly sliced red onion, potatoes and pan sauce. Stir to loosen browned bits from the bottom of the pan. Allow the red onion to soften slightly, about 2-3 minutes.
Nestle pork chops into the potato-onion mixture, and place the dutch oven into the oven (no lid). Cook until pork chops are completely cooked through and reach an internal temperature of 145ºF, about 10 minutes. Pork chops may reach the internal temperature of 145°F before the potatoes are fork tender. If this occurs, remove pork chops from the Dutch oven and continue to cook potatoes and onions until the potatoes are cooked through.
Remove the dutch oven from the oven, and place pork chops onto a cutting board.
Add the kale to the potatoes and red onion, and stir until wilted, about 1-2 minutes.Taste and season as necessary. Option to add black pepper or red pepper flakes.
Split between two plates. Slice pork chops and divide onto plates. Serve warm.